Research press release


Scientific Reports

Archaeology: Modern pesticide accelerates corrosion of ancient Roman bowl

後期鉄器時代(西暦43~410年)のものとされる腐食したローマ時代の鋺(金属製の椀)にクロロベンゼンの痕跡が見つかった。クロロベンゼンは、かつて農薬に使用されていた化学物質で、土壌や水源に蓄積することが知られている。今回の研究では、クロロベンゼンで汚染された土壌が、地中に残っている考古学的材料の保存を脅かしている可能性があることが明らかになった。こうした知見を報告する論文が、Scientific Reports に掲載される。


今回、Luciana da Costa Carvalhoたちは、この鋺に見られる緑色と褐色の腐食を分析し、それぞれの成分を特定した。その結果、人間の活動によって引き起こされた土壌の経時変化を示す成分が発見された。つまり、緑色の腐食にはクロロベンゼンが存在することが判明し、褐色の腐食にはジエチルトルアミド(DEETとも呼ばれる)が発見された。ジエチルトルアミドは、防虫剤に使用されている現代の化合物だ。


A corroded Roman bowl dated to the Late Iron Age (between 43 and 410 AD) contains traces of chlorobenzenes, a chemical once used in pesticides that is known to accumulate in soil and water sources. The study, published in Scientific Reports, highlights that soil polluted with chlorobenzenes may pose a continuing threat to the preservation of archaeological material still in the ground.

Chlorobenzenes are synthetic compounds that can be toxic at high levels and most have been prohibited for use in the UK following concerns being raised about environmental pollution. These compounds are thought, however, to have accumulated in the environment through previous agricultural and industrial activities. A Roman bowl, made of a copper-alloy, was found in 2016 on a farm in Kent (UK), a site that was known to have been used for agriculture since at least 1936.

Luciana da Costa Carvalho and colleagues analysed the green and brown-coloured corrosion on the bowl to identify their different components. They found elements that were indicative of the changes over time in the soil caused by human activities. In the green-coloured corrosion, the authors found chlorobenzenes were present. The authors also found diethyltoluamide (also known as DEET) in the brown-coloured corrosion, a modern compound that is still used in insect repellents.

The authors suggest that the chlorobenzenes were associated with increased corrosion in the Roman bowl. They conclude that even though chlorobenzenes are no longer used in the UK, polluted soil may still threaten the preservation of archaeological material still buried and more research needs to be undertaken to better understand the processes involved.

doi: 10.1038/s41598-022-17902-9


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